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khoom

1-Bromobutane (CAS # 109-65-9)

Chemical Property:

Molecular Formula c4h9 wb
Molar Mass 137.02 Nws
Qhov ntom 1.276g / mLat 25 ° C (lit.)
Melting Point -112 ° C
Boling Point 100-104 ° C (lit.)
Flash Point 23 ° C
Dej Solubility 0.608 g / L (30 ºC)
Solubility 0.6g / l
Vapor Siab 150 hli Hg (50 ° C)
Vapor Density 4.7 (vs dej)
Qhov tshwm sim Ua kua
Xim Ntshiab xim tsis muaj xim rau lub teeb daj
tsw tus cwj pwm tsw
Merck 14 Ib., 1553
BRN 1098260 ib
Kev cia khoom Khaws hauv qab +30 ° C.
Kev ruaj ntseg ruaj khov. Flammable - nco ntsoov tsawg flash point. Incompatible nrog muaj zog oxidizing neeg sawv cev, muaj zog hauv paus.
Explosive txwv 2.8-6.6%, 100 ° F
Refractive Index n20/D 1.439 (lit.)
Physical thiab Chemical Properties Cov khoom no tsis muaj xim, pob tshab thiab muaj ntxhiab kua, MP-112 ℃, B. p.100 ~ 104 ℃, n20D 1.4390, txheeb ze ntom ntom 1.276, f. P.75f (23 ℃), insoluble hauv dej, soluble hauv cawv, ether thiab chloroform thiab lwm yam organic solvents.
Siv Siv ua tshuaj, zas xim, tshuaj tua kab intermediates

Product Detail

Khoom cim npe

Risk Codes R11 - Cov nplaim hluav taws kub heev
R36/37/38 - Kab mob rau qhov muag, ua pa thiab tawv nqaij.
R51/53 - Cov tshuaj lom rau cov kab mob hauv dej, tuaj yeem ua rau muaj kev cuam tshuam ntev rau hauv dej hiav txwv.
R10 - Flammable
Kev nyab xeeb piav qhia S16 - Khaws kom deb ntawm qhov chaw hluav taws xob.
S26 - Thaum sib cuag nrog lub qhov muag, yaug tam sim ntawd nrog dej txaus thiab nrhiav kev kho mob.
S60 - Cov khoom no thiab nws lub thawv yuav tsum tau muab pov tseg raws li cov khoom pov tseg.
S37/39 - Hnav cov hnab looj tes tsim nyog thiab tiv thaiv qhov muag / ntsej muag
UN IDs UN 1126 3/PG 2
WGK Germany 2
RTECS EJ 6225 000
TSCA Yog lawm
HS Code 29033036 ib
Hazard Class 3
Packing Group II
Toxicity LD50 qhov ncauj hauv Luav: 2761 mg / kg

 

Taw qhia

1-Bromobutane yog cov kua tsis muaj xim nrog cov ntxhiab tsw ntxhiab tsw. Bromobutane muaj nruab nrab volatility thiab vapor siab, soluble nyob rau hauv organic solvents, thiab insoluble nyob rau hauv dej.

 

1-Bromobutane yog dav siv los ua brominating reagent hauv organic synthesis. Nws tuaj yeem siv los ua lub substrate rau cov tshuaj tiv thaiv brominated xws li cov tshuaj tiv thaiv nucleophilic hloov pauv, tshem tawm cov tshuaj tiv thaiv, thiab rov kho cov tshuaj tiv thaiv. Nws kuj tseem siv tau los ua cov kuab tshuaj ua lag luam, piv txwv li hauv roj av extraction kom tshem tawm cov quav ciab los ntawm cov roj av. Nws yog khaus thiab lom, thiab yuav tsum tau ceev faj thiab nruab nrog kev ceev faj tsim nyog thaum siv.

 

Ib txoj hauv kev zoo rau kev npaj ntawm 1-bromobutane yog los ntawm cov tshuaj tiv thaiv ntawm n-butanol nrog hydrogen bromide. Cov tshuaj tiv thaiv no yog nqa tawm nyob rau hauv acidic tej yam kev mob los tsim 1-bromobutane thiab dej. Cov kev mob tshwm sim tshwj xeeb thiab kev xaiv ntawm catalyst yuav cuam tshuam rau cov txiaj ntsig thiab kev xaiv ntawm cov tshuaj tiv thaiv.

Nws ua rau khaus ntawm daim tawv nqaij thiab qhov muag, thiab nqus tau ntau dhau tuaj yeem ua rau ua pa nyuaj thiab puas hlwb. Nws yuav tsum tau ua nyob rau hauv ib qho chaw zoo-ventilated thiab nrog cov hnab looj tes tiv thaiv, tsom iav, thiab lub tshuab ua pa hnav. Thaum khaws cia thiab tuav, cia kom deb ntawm qhov hluav taws kub thiab oxidants kom tsis txhob muaj hluav taws kub thiab tawg.


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