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1-Butanol (CAS # 71-36-3)

Chemical Property:

Molecular Formula C4H10O
Molar Mass 74.12 ib
Qhov ntom 0.81 g / mL ntawm 25 ° C (lit.)
Melting Point -90 ° C (lit.)
Boling Point 116-118 ° C (lit.)
Flash Point 95 ° F
JECFA Number 85
Dej Solubility 80 g / L (20 ºC)
Solubility Soluble hauv DMSO
Vapor Siab 6.7 hPa (20 ° C)
Vapor Density 2.55 (vs huab cua)
Qhov tshwm sim Dawb hmoov
Xim PIB: ≤10
tsw Cawv zoo li cawv; pungent; muaj zog; yam ntxwv; me ntsis cawv, tsis residual.
Exposure Limit TLV-TWA 300 mg/m3 (100 ppm) (NIOSH), 150 mg/m3 (50 ppm) (ACGIH); IDLH 8000ppm (NIOSH).
Qhov siab tshaj plaws wavelength (λmax) λ: 215 nm Amax: 1.00λ: 220 nm Amax: 0.50λ: 240 nm Amax: 0.10λ: 260 nm Amax: 0.04λ: 280-400 nm Amax:
Merck 14 Ib., 1540
BRN 969148 ib
pKa 15.24 ± 0.10 (Kev kwv yees)
PH 7 (70g / l, H2O, 20 ℃)
Kev cia khoom Khaws ntawm +5 ° C rau + 30 ° C.
Kev ruaj ntseg ruaj khov. Incompatible nrog muaj zog acids, muaj zog oxidizing neeg sawv cev, aluminium, acid chlorides, acid anhydrides, tooj liab, tooj liab alloys. Flamable.
rhiab heev Moisture Sensitive
Explosive txwv 1.4-11.3% (V)
Refractive Index n20/D 1.399 (lit.)
MDL PAB 00002902
Physical thiab Chemical Properties Cov yam ntxwv ntawm cov kua tsis muaj xim, nrog saj ntawm cawv.
melting point -90.2 ℃
Kub taw tes 117.7 ℃
txheeb ze ntom ntom 0.8109
Refractive Index 1.3993
flash point 35 ~ 35.5 ℃
solubility ntawm 20 ℃ solubility hauv dej 7.7% los ntawm qhov hnyav, solubility ntawm dej hauv n-butanol yog 20.1% los ntawm qhov hnyav. Miscible nrog ethanol, ether thiab lwm yam organic solvents.
Siv Siv nyob rau hauv zus tau tej cov butyl acetate, dibutyl phthalate thiab phosphoric acid plasticizer, kuj siv nyob rau hauv zus tau tej cov melamine resin, acrylic acid, epoxy varnish, thiab lwm yam

Product Detail

Khoom cim npe

Risk Codes R10 - Flammable
R22 - Ua phem yog tias nqos
R37/38 - Kab mob ua pa thiab tawv nqaij.
R41 - Riam phom loj rau qhov muag
R67 - Vapors tuaj yeem ua rau qaug zog thiab kiv taub hau
R39/23/24/25 -
R23/24/25 – Toxic los ntawm inhalation, nyob rau hauv kev sib cuag nrog daim tawv nqaij thiab yog hais tias nqos.
R11 - Cov nplaim hluav taws kub heev
Kev nyab xeeb piav qhia S13 - Cia kom deb ntawm cov zaub mov, dej haus thiab cov khoom noj tsiaj.
S26 - Thaum sib cuag nrog lub qhov muag, yaug tam sim ntawd nrog dej txaus thiab nrhiav kev kho mob.
S37/39 - Hnav cov hnab looj tes tsim nyog thiab tiv thaiv qhov muag / ntsej muag
S46 - Yog tias nqos tau, nrhiav kev kho mob tam sim ntawd thiab qhia lub thawv lossis daim ntawv lo.
S7/9 -
S45 - Thaum muaj xwm txheej lossis yog tias koj tsis xis nyob, nrhiav kev kho mob tam sim ntawd (qhia daim ntawv lo thaum twg ua tau.)
S36/37 - Hnav cov khaub ncaws tiv thaiv thiab hnab looj tes tsim nyog.
S16 - Khaws kom deb ntawm qhov chaw hluav taws xob.
S7 - Khaws lub thawv kaw kom nruj.
UN IDs UN 1120 3/PG 3
WGK Germany 1
RTECS EO 1400000
TSCA Yog lawm
HS Code 2905 13 00 Nws
Hazard Class 3
Packing Group III
Toxicity LD50 ntawm qhov ncauj hauv nas: 4.36 g / kg (Smyth)

 

Taw qhia

N-butanol, tseem hu ua butanol, yog cov organic compound, nws yog cov kua tsis muaj xim nrog cov ntxhiab tsw ntxhiab tsw. Cov hauv qab no yog kev qhia txog cov khoom, kev siv, kev npaj thiab cov ntaub ntawv kev nyab xeeb ntawm n-butanol:

 

Zoo:

1. Lub cev muaj zog: Nws yog cov kua tsis muaj xim.

2. Cov khoom siv tshuaj lom neeg: Nws tuaj yeem yaj hauv dej thiab cov kuab tshuaj organic, thiab yog ib qho chaw nruab nrab ntawm cov polar compound. Nws tuaj yeem raug oxidized rau butyraldehyde thiab butyric acid, los yog nws tuaj yeem dehydrated los ua butene.

 

Siv:

1. Muaj kev siv: Nws yog ib qho hnyav hnyav thiab muaj ntau yam kev siv hauv kev lag luam tshuaj xws li coatings, inks, thiab detergents.

2. Kev siv hauv chav kuaj: Nws tuaj yeem siv los ua cov kuab tshuaj los ua kom muaj helical protein folding, thiab feem ntau yog siv rau hauv kev sim tshuaj biochemical los catalyze cov tshuaj tiv thaiv.

 

Txoj kev:

1. Butylene hydrogenation: Tom qab hydrogenation cov tshuaj tiv thaiv, butene yog reacted nrog hydrogen nyob rau hauv lub xub ntiag ntawm ib tug catalyst (xws li ib tug nickel catalyst) kom tau n-butanol.

2. Cov tshuaj tiv thaiv lub cev qhuav dej: butanol yog reacted nrog cov acids muaj zog (xws li concentrated sulfuric acid) los tsim butene los ntawm lub cev qhuav dej, thiab ces butene yog hydrogenated kom tau n-butanol.

 

Cov ntaub ntawv kev nyab xeeb:

1. Nws yog cov kua hluav taws kub, tsis txhob sib cuag nrog qhov hluav taws kub, thiab kom deb ntawm cov nplaim taws thiab qhov chaw kub kub.

3. Nws muaj qee yam toxicity, tsis txhob kov ncaj qha rau ntawm daim tawv nqaij thiab qhov muag, thiab tsis txhob nqus nws vapor.

4. Thaum khaws cia, nws yuav tsum muab cia rau hauv qhov chaw kaw, kom deb ntawm cov oxidants thiab hluav taws kub, thiab khaws cia rau hauv chav tsev kub.


  • Yav dhau los:
  • Tom ntej:

  • Sau koj cov lus ntawm no thiab xa tuaj rau peb