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Allyl mercaptan (2-propen-1-thiol) (CAS # 870-23-5)

Chemical Property:

Molecular Formula C3H6S
Molar Mass 74.14 ib
Qhov ntom 0.898 g / mL ntawm 25 ° C (lit.)
Melting Point 175-176 ° C (Solv: benzene (71-43-2))
Boling Point 67-68 ° C (lit.)
Flash Point 18 ° C
JECFA Number 521 ib
Solubility Tsis miscible los yog nyuaj rau mix.
Vapor Siab 152 mmHg ntawm 25 ° C
Qhov tshwm sim Ua kua
Xim Ntshiab xim tsis muaj xim rau lub teeb daj
BRN 1697523 ib
pKa 9.83 ± 0.10 (Kev kwv yees)
Kev cia khoom -20 ° C
Kev ruaj ntseg Stable, tab sis heev flammable. Incompatible nrog cov hauv paus muaj zog, muaj zog oxidizing cov neeg ua haujlwm, cov hlau reactive.
rhiab heev Huab cua Sensitive
Refractive Index n20/D 1.4765 (lit.)
Physical thiab Chemical Properties Colorless rau lub teeb daj flowable kua. Ib qho muaj zog qej thiab dos tsw, qab zib, tsis ua rau mob. Boiling point ntawm 66 ~ 68 deg C. Me ntsis soluble hauv dej, miscible hauv ethanol, ether thiab roj. Cov khoom ntuj muaj nyob hauv dos, qej, thiab lwm yam.

Product Detail

Khoom cim npe

Hazard Cov Cim F - Flammable
Risk Codes 11 - Cov nplaim hluav taws kub heev
Kev nyab xeeb piav qhia S16 - Khaws kom deb ntawm qhov chaw hluav taws xob.
S33 - Siv cov kev tiv thaiv kev tiv thaiv zoo li qub.
S9 - Khaws lub thawv rau hauv qhov chaw muaj cua zoo.
UN IDs UN 1228 3/PG 2
WGK Germany 3
FLUKA BRAND F CODE 10-13-23 : kuv
TSCA Yog lawm
HS Code 29 3090 ,ib
Hazard Class 3
Packing Group II

 

Taw qhia

Allyl mercaptans.

 

Zoo:

Allyl mercaptan yog cov kua tsis muaj xim nrog cov ntxhiab tsw. Nws tuaj yeem yaj hauv cov kuab tshuaj organic xws li cawv, ethers, thiab cov kuab tshuaj hydrocarbon. Allyl mercaptans oxidize yooj yim, tig daj thaum raug huab cua ntev, thiab txawm tsim disulfides. Nws tuaj yeem koom nrog ntau yam kev cuam tshuam cov organic, xws li nucleophilic ntxiv, esterification cov tshuaj tiv thaiv, thiab lwm yam.

 

Siv:

Allyl mercaptans feem ntau yog siv rau qee qhov kev cuam tshuam tseem ceeb hauv cov organic synthesis. Nws yog ib qho substrate rau ntau cov enzymes lom thiab tuaj yeem siv rau hauv kev tshawb fawb lom neeg thiab kev kho mob. Allyl mercaptan tseem tuaj yeem siv los ua cov khoom siv raw hauv kev tsim cov diaphragm, iav thiab roj hmab, nrog rau cov khoom muaj nyob hauv cov tshuaj tua kab mob, cov nroj tsuag kev loj hlob regulators thiab surfactants.

 

Txoj kev:

Feem ntau, allyl mercaptans tuaj yeem tau txais los ntawm reacting allyl halides nrog hydrogen sulfide. Piv txwv li, allyl chloride thiab hydrogen sulfide react nyob rau hauv lub xub ntiag ntawm lub hauv paus los ua ib tug allyl mercaptan.

 

Cov ntaub ntawv kev nyab xeeb:

Allyl mercaptans yog tshuaj lom, irritating thiab corrosive. Kev sib cuag ntawm daim tawv nqaij thiab qhov muag yuav ua rau khaus thiab kub hnyiab. Cov hnab looj tes tiv thaiv, tsom iav, thiab khaub ncaws tiv thaiv yuav tsum hnav thaum siv lossis tuav. Tsis txhob nqus nws cov vapors los yog nkag mus rau ntawm daim tawv nqaij. Kev ua pa zoo yuav tsum tau khaws cia thaum lub sijhawm ua haujlwm kom tsis txhob muaj ntau tshaj qhov txwv tsis pub muaj kev nyab xeeb.


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  • Sau koj cov lus ntawm no thiab xa tuaj rau peb