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Chloroacetyl chloride (CAS # 79-04-9)

Chemical Property:

Molecular Formula C2H2Cl2O
Molar Mass 112.94 Nws
Qhov ntom 1.419g / mLat 20 ° C
Melting Point -22 ° C (lit.)
Boling Point 105-106 ° C (lit.)
Flash Point > 100 ° C
Dej Solubility reacts
Solubility Miscible nrog ethyl ether, acetone, benzene thiab carbon tetrachloride.
Vapor Siab 60 mm Hg (41.5 ° C)
Vapor Density 3.9 (vs huab cua)
Qhov tshwm sim Ua kua
Xim Ntshiab xim tsis muaj xim kom daj me ntsis
Exposure Limit ACGIH: TWA 0.05 ppm; STEL 0.15 ppm (Daim tawv nqaij) NIOSH: IDLH 1.3 ppm; TWA 0.05 ppm (0.2 mg/m3)
Merck 14 Ib., 2067
BRN 605439 ib
Kev cia khoom Khw hauv RT.
Kev ruaj ntseg ruaj khov. Incompatible nrog muaj zog hauv paus, cawv, muaj zog oxidizing tus neeg sawv cev. Tej zaum yuav hnov ​​​​mob hnyav thaum raug dej lossis dej noo.
rhiab heev Moisture Sensitive
Refractive Index n20/D 1.453 (lit.)
Physical thiab Chemical Properties Cov yam ntxwv ntawm cov kua dej tsis muaj xim lossis daj daj, muaj qhov ua kom khaus khaus.
melting point
Kub taw tes 107 ℃
khov taw tes -22.5 ℃
txheeb ze ntom ntom 1.4202
Refractive Index 1.4530
solubility: soluble nyob rau hauv benzene, carbon tetrachloride, ether thiab chloroform.
Siv Siv nyob rau hauv cov tshuaj, tshuaj tua kab, kuj yuav siv tau raws li extraction hnyav, refrigerant, dye pab thiab lubricating roj additives

Product Detail

Khoom cim npe

Risk Codes R14 - Reacts hnyav nrog dej
R23/24/25 – Toxic los ntawm inhalation, nyob rau hauv kev sib cuag nrog daim tawv nqaij thiab yog hais tias nqos.
R35 - Ua rau kub hnyiab heev
R48/23 -
R50 - Muaj tshuaj lom rau cov kab mob hauv dej
R29 - Sib cuag nrog dej liberates cov pa phem
Kev nyab xeeb piav qhia S9 - Khaws lub thawv rau hauv qhov chaw muaj cua zoo.
S26 - Thaum sib cuag nrog lub qhov muag, yaug tam sim ntawd nrog dej txaus thiab nrhiav kev kho mob.
S36/37/39 - Hnav cov khaub ncaws tiv thaiv tsim nyog, hnab looj tes thiab tiv thaiv qhov muag / ntsej muag.
S45 - Thaum muaj xwm txheej lossis yog tias koj tsis xis nyob, nrhiav kev kho mob tam sim ntawd (qhia daim ntawv lo thaum twg ua tau.)
S61 - Tsis txhob tso tawm rau ib puag ncig. Xa mus rau cov lus qhia tshwj xeeb / cov ntaub ntawv kev nyab xeeb.
S7/8 -
UN IDs UN 1752 6.1/PG 1
WGK Germany 3
RTECS TIAB SA 6475000
TSCA Yog lawm
HS Code 29159000 ib
Hazard Class 6.1
Packing Group I

 

Taw qhia

Monochloroacetyl chloride (tseem hu ua chloroyl chloride, acetyl chloride) yog cov organic compound. Nws cov khoom yog raws li nram no:

 

1. Cov tsos mob: tsis muaj xim lossis daj daj;

2. Cov ntxhiab tsw: tshwj xeeb pungent tsw;

3. Ceev: 1.40 g / mL;

 

Monochloroacetyl chloride feem ntau yog siv rau hauv cov organic synthesis thiab muaj cov hauv qab no siv:

 

1. Raws li acylation reagent: nws tuaj yeem siv rau cov tshuaj tiv thaiv esterification, uas reacts acid nrog cawv los ua ester;

2. Raws li acetylation reagent: nws tuaj yeem hloov cov active hydrogen atom nrog ib pab pawg acetyl, xws li kev taw qhia ntawm acetyl functional pawg hauv cov tshuaj tsw qab;

3. Raws li chlorinated reagent: nws tuaj yeem ua kom paub cov tshuaj chlorine atoms sawv cev ntawm chloride ions;

4. Nws yog siv los npaj lwm cov organic tebchaw, xws li ketones, aldehydes, acids, thiab lwm yam.

 

Monochloroacetyl chloride feem ntau yog npaj raws li hauv qab no:

 

1. Nws yog npaj los ntawm cov tshuaj tiv thaiv ntawm acetyl chloride thiab trichloride, thiab cov khoom siv tshuaj tiv thaiv yog monochloroacetyl chloride thiab trichloroacetic acid:

C2H4O + Cl2O3 → CCl3COCl + ClOCOOH;

2. Cov tshuaj tiv thaiv ncaj qha ntawm acetic acid nrog chlorine los tsim monochloroacetyl chloride:

C2H4O + Cl2 → CCl3COCl + HCl.

 

Thaum siv monochloroacetyl chloride, cov ntaub ntawv kev nyab xeeb hauv qab no yuav tsum raug sau tseg:

 

1. Nws muaj cov ntxhiab tsw ntxhiab thiab chav, thiab yuav tsum tau ua haujlwm hauv qhov chaw muaj cua zoo;

2. Txawm hais tias nws tsis yog nplaim taws, nws yuav hnov ​​​​mob hnyav thaum nws ntsib qhov hluav taws kub, ua rau cov pa phem, thiab yuav tsum tau ceev kom tsis txhob muaj hluav taws kub hnyiab;

3. Thaum siv thiab khaws cia, nws yog ib qho tsim nyog kom tsis txhob muaj kev sib cuag nrog cov oxidants muaj zog, alkalis, hlau hmoov thiab lwm yam khoom los tiv thaiv kev txaus ntshai;

4. Nws yog khaus rau ntawm daim tawv nqaij, qhov muag thiab ua pa, thiab yuav tsum tau ua nrog cov hnab looj tes, tsom iav thiab cov qhov ncauj qhov ntswg tiv thaiv;

5. Nyob rau hauv rooj plaub ntawm kev nqus pa los yog kev sib cuag, ntxuav qhov chaw raug mob tam sim ntawd thiab nrhiav kev pab kho mob yog tias muaj cov tsos mob.


  • Yav dhau los:
  • Tom ntej:

  • Sau koj cov lus ntawm no thiab xa tuaj rau peb