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Thiophenol (CAS # 108-98-5)

Chemical Property:

Molecular Formula C6H6S
Molar Mass 110.18 Nws
Qhov ntom 1.078 ib
Melting Point -15 ° C
Boling Point 169 ° C (lit.)
Flash Point 123 ° F
JECFA Number 525
Dej Solubility insoluble
Solubility DMSO, Ethyl Acetate
Vapor Siab 1.4 hli Hg (20 ° C)
Vapor Density 3.8 (vs huab cua)
Qhov tshwm sim Ua kua
Xim Ntshiab xim tsis muaj xim kom daj me ntsis
tsw Tsis kaj siab
Exposure Limit TLV-TWA 0.5 ppm (~2.5 mg/m3) (ACGIH).
Merck 14, 9355 ib
BRN 5 06523
pKa 6.6 (ntawm 25 ℃)
Kev cia khoom Khw hauv RT.
Kev ruaj ntseg ruaj khov. Flamable. Tej zaum yuav tsim cov khoom tawg nrog cua. Stench. Incompatible nrog muaj zog oxidizing neeg sawv cev.
rhiab heev Stench
Refractive Index n20/D 1.588 (lit.)
Physical thiab Chemical Properties Colorless rau dej-dawb los yog lub teeb daj flowable kua. Muaj ib qho tsis kaj siab diffuse qej zoo li tsw. Boiling point 169 °c, lossis 46.4 °c (1333Pa). Insoluble hauv dej, me ntsis soluble hauv ethanol thiab ether, soluble hauv roj. Ntuj cov khoom muaj nyob rau hauv boiled nqaij nyuj.
Siv Siv ua tshuaj Intermediate

Product Detail

Khoom cim npe

Risk Codes R10 - Flammable
R24/25 -
R26 - Mob heev los ntawm kev nqus pa
R41 - Riam phom loj rau qhov muag
R36/37/38 - Kab mob rau qhov muag, ua pa thiab tawv nqaij.
Kev nyab xeeb piav qhia S23 - Tsis txhob ua pa.
S26 - Thaum sib cuag nrog lub qhov muag, yaug tam sim ntawd nrog dej txaus thiab nrhiav kev kho mob.
S28 - Tom qab sib cuag nrog daim tawv nqaij, ntxuav tam sim nrog xab npum-suds ntau.
S36/37/39 - Hnav cov khaub ncaws tiv thaiv tsim nyog, hnab looj tes thiab tiv thaiv qhov muag / ntsej muag.
S45 - Thaum muaj xwm txheej lossis yog tias koj tsis xis nyob, nrhiav kev kho mob tam sim ntawd (qhia daim ntawv lo thaum twg ua tau.)
S28A -
S16 - Khaws kom deb ntawm qhov chaw hluav taws xob.
UN IDs UN 2337 6.1/PG 1
WGK Germany 3
RTECS DC0525000
FLUKA BRAND F CODE 10-13-23 : kuv
TSCA Yog lawm
HS Code 293 099 ib
Kev Ceeb Toom Toxic/Stench
Hazard Class 6.1
Packing Group I

 

Taw qhia

Phenophenol, tseem hu ua benzene sulfide, yog xim tsis muaj xim rau lub teeb daj. Cov hauv qab no yog kev qhia txog cov khoom, kev siv, kev npaj thiab cov ntaub ntawv kev nyab xeeb ntawm phenol:

 

Zoo:

- Cov tsos mob: Phenophenol yog cov xim tsis muaj xim rau lub teeb daj nrog cov ntxhiab tsw ntxhiab thiophenol.

- Solubility: Phenophenol yog insoluble hauv dej, tab sis soluble nyob rau hauv ntau cov organic solvents xws li cawv, ethers, cawv ethers, thiab lwm yam.

- Reactivity: Phenophenol yog electrophilic thiab muaj peev xwm undergo acid-base neutralization, oxidation, thiab hloov.

 

Siv:

- Kev lag luam tshuaj: Phenophenol tuaj yeem siv los ua qhov nruab nrab hauv kev tsim cov dyes, plastics, thiab roj hmab.

- Cov tshuaj tua kab mob: Phenol muaj qee yam tshuaj tua kab mob, pwm inhibition thiab tshuaj tua kab mob, thiab yog siv dav hauv kev tiv thaiv ntoo, pleev xim, nplaum thiab lwm yam.

 

Txoj kev:

Phenol tuaj yeem npaj los ntawm cov tshuaj tiv thaiv ntawm benzenesulfonyl chloride nrog sodium hydrosulfide. Hauv cov tshuaj tiv thaiv, benzenesulfonyl chloride reacts nrog sodium hydrogen sulfide los ua benzene mercaptan, uas tom qab ntawd oxidized kom tau phenylthiophenol.

 

Cov ntaub ntawv kev nyab xeeb:

- Phenophenol ua rau khaus thiab tuaj yeem ua rau mob rau ntawm daim tawv nqaij lossis qhov muag. Kev sib cuag ncaj qha rau ntawm daim tawv nqaij thiab qhov muag yuav tsum zam thaum siv thiophenol, thiab cov hnab looj tes tiv thaiv thiab tsom iav yuav tsum hnav yog tias tsim nyog.

- Phenophenol yog tshuaj lom rau ib puag ncig thiab yuav tsum zam kom tsis txhob muaj qhov dej loj thiab tawm mus rau hauv dej los yog av.

- Phenophenol yog volatile thiab tej zaum yuav ua rau cov tsos mob xws li kiv taub hau thiab xeev siab yog tias raug rau nws nyob rau hauv ib tug unventilated ib puag ncig ntev. Ib qho chaw ua haujlwm tau zoo yuav tsum tau khaws cia thaum siv phenothiophenol.


  • Yav dhau los:
  • Tom ntej:

  • Sau koj cov lus ntawm no thiab xa tuaj rau peb